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杨海斌

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个人简述

海斌,博士,副教授20192月广东工业大学青年百人计划”A层次引进加入轻工化工学院, 长期从事于有机合成方法学研究,在不对称有机催化,过渡金属催化,自由基反应以及光催化等领域有着丰富经验。以第一作者在ACS Catal; Chem. Eur. JAdv. Synth. CatalChem. CommunJ. Org. ChemOrg.Biomol.Chem等国际SCI期刊发表论文11篇;合作在Angew. Chem. Int. EdChem. Eur. JAdv. Synth. Catal等国际SCI期刊发表论文5篇;1篇论文被Synfacts亮点评述;1篇论文入选ESI高被引论文。论文总引用超过300多次。

联系方式:

984816350@qq.com    haibiny@gdut.edu.cn

教育背景:

2004/09-2008/07湖南师范大学,药学,学士

2010/09-2015/07中科院上海有机化学研究所有机化学导师:施敏研究员

科研经历:

2011/06-2015/07,中国科学院上海有机化学研究所,金属有机化学国家重点实验室,导师:施敏研究员

2015/10-2017/10,瑞典斯德哥尔摩大学,有机化学系,博士后,合作导师:Nicklas Selander教授

2017/10-2018/12美国加州大学河滨分校,化学系,博士后,合作导师:David B.C. Martin教授

研究领域:

(1)光介导的自由基反应

(2)不对称催化

(3)过渡金属催化的新型有机化学反应

科研项目:

1瑞典Wenner-Gren基金铁催化的新型偶联反应及配体设计,2015-201760万克朗已结题

代表性论文及著作:

[1] Yang, H.-B.; Feceu, A.; Martin, D. B. C. * Catalyst-Controlled C–H Functionalization of Adamantanes using Selective H-Atom Transfer”. Submitted. [ChemRxiv preprint].

[2] Yang, H.-B.; Pathipati, S. R.; Selander, N.* “Nickel-Catalyzed 1,2-Aminoarylation of Oxime Ester-Tethered Akenes with Boronic Acids”. ACS Catal. 2017, 7, 8441-8445. (JCR一区, top期刊).

[3] Yang, H.-B.; Selander, N.* Divergent Iron-Catalyzed Coupling of O-Acyloximes with Silyl Enol Ethers. Chem. Eur. J.2017, 23, 1779-1783. (JCR二区, top期刊)

Highlighted in Synfacts (2017, 13, 0350);ESI “Highly Cited Paper”.

[4] Yang, H.-B.; Selander, N.* A redox-economical synthesis of trifluoromethylated enamides with the Langlois reagent. Org.Biomol. Chem. 2017, 15, 1771-1775. (JCR二区)

[5] Yang, H.-B.; Yuan, Y.-C.; Wei, Y.*; Shi, M.* Amine-catalyzed tunable reactions of allenoates with dithioesters: formal [4+2] and [2+2] cycloadditions for the synthesis of 2,3-dihydro-1,4-oxathiines and enantioenriched thietanes. Chem. Commun. 2015, 51, 6430-6433. (JCR一区, top期刊)

[6] Yang, H.-B.; Zhao, Y.-Z.; Sang, R.; Wei, Y.*; Shi, M.*, Asymmetric Synthesis of Bioxindole-Substituted Hexahydrofuro[2,3-b]furans via Hydroquinine Anthraquinone-1,4-diyl Diether-Catalyzed Domino Annulation of Acylidenoxindoles/Isatins,Acylidenoxindoles and Allenoates”. Adv. Synth. Catal. 2014, 356, 3799-3808. (JCR一区, top 期刊)

[7] Yang, H.-B.; Zhao, Y.-Z.; Sang, R.; Shi, M.*, “(DHQ)2AQN-Catalyzed Asymmetric Substitution of Isatin-Derived Hydrazones with O-Boc-Protected Morita-Baylis-Hillman Adducts: A Strategy for Synthesizing Enantioenriched Azo Compounds Incorporating an Oxindole Scaffold”. J. Org. Chem .2014, 79, 3519-3528. (JCR 二区, top 期刊)

[8] Yang, H.-B.; Fan, X.; Wei, Y.*; Shi, M.*, “Solvent-controlled nucleophilic trifluoromethylthiolation of Morita–Baylis–Hillman carbonates: dual roles of DABCO in activating the Zard’s trifluoromethylthiolation reagent and the MBH carbonates”. Org. Chem. Front. 2015, 2, 1088-1093. (JCR 二区)

[9] Yang, H.-B.; Guan, X.-Y.; Wei, Y., Shi, M.*, “A Three-Component Condensation for the Construction of the Spiro[indoline-3,3′-piperidin]-2-one Skeleton”. Eur. J. Org. Chem. 2012, 2792-2800. (JCR 三区)

[10] Yang, H.-B.; Zhao, Y.-Z.; Sang, R.; Tang, X.-Y., Shi, M.*, “A novel multicomponent reaction involving isoquinoline, allenoate and activated ketone”. Tetrahedron, 2013, 69, 9205-9211. (JCR 三区)

[11] Yang, H.-B.; Wei, Y.*; Shi, M.*, “Construction of spiro[indoline]oxindoles through one-pot thermal-induced [3+2] cycloaddition/silica gel-promoted fragmentation sequence between isatin ketonitrones and electron-deficient alkynes”. Tetrahedron, 2013, 69, 4088-4097. (JCR 三区)

[12] Yang, H.-B.; Shi, M.*, “Yb(NTf2)3-catalyzed [3+3] cycloaddition between isatin ketonitrones and cyclopropanes to construct novel spiro[tetrahydro-1,2-oxazine]oxindoles”. Org. Biomol. Chem. 2012, 10, 8236-8243. (JCR二区)

 

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