李先纬, 男,博士,副教授,广东工业大学青年百人A引进。主要研究方向为:金属有机化学,绿色化学导向的有机合成及其在有机光电材料中的应用,在Angew. Chem. Int. Ed.,Chem. Sci.,ACS Catal., Sci. Chin. Chem.,等高水平国际期刊上发表论文50余篇,授权专利10余项,相关成果参与华南理工大学江焕峰教授主持的教育部自然科学进步一等奖。
联系方式:Email: xwli@gdut.edu.cn; Tel: 15989188462
教育背景:
2016.7–至今 广东工业大学 轻工化工学院,“青年百人A类”引进,副教授
2019.3–2020.3 麦吉尔大学(McGill University)访问学者,合作导师:李朝军(Chao-Jun Li)教授(加拿大科学院院士)
2014. 7–2016-7 南开大学元素有机国家重点实验室,北京大学化学与分子工程学院,博士后,合作导师:梁广鑫教授,施章杰教授(国家杰青,教育部长江学者)
2009. 9–2014. 6 华南理工大学,博士(硕博连读),导师:江焕峰 教授(国家杰青)
2005.09–2009.06 安徽工业大学,本科
主持的科研项目:
国家级科研项目:
1、 国家自然科学基金面上项目:基于金属催化有序碳氢键和碳碳键活化策略构建稠杂环;项目批准号:22071034,2021-2024,主持;
2、 国家自然科学基金青年项目:基于钌–铜双金属催化惰性C–H键和醇类C–O键的炔基化反应研究;项目批准号:21602032,2017-2019,主持;
部分科研论文:
1. Xianwei Li, Xiaohang Liu, Huoji Chen, Wanqing Wu, Chaorong Qi, Huanfeng Jiang*. Copper-Catalyzed Aerobic Oxidative Transformation of Ketone-Derived N-Tosyl Hydrazones: An Entry to Alkynes. Angew. Chem. Int. Ed. 2014, 53, 14485–144895. (IF: 16.823)
2. Xianwei Li,* Jianhang Rao, Wensen Ouyang, Qian Chen, Ning Cai, Yu-Jing Lu, Yanping Huo. Sequential C − H and C−C Bond Cleavage: Divergent Constructions of Fused N‑Heterocycles via Tunable Cascade, ACS Catal., 2019, 9, 8749−8756. (IF: 13.700)
3. Xianwei Li, Chao-Jun Li*, A Cu/Cinchona P, N-ligand System Enabled General Asymmetric C(sp3)–C(sp) Coupling, Sci. China Chem., 2020, 63, 751-752. (IF: 10.138)
4. Xianwei Li, Liangbin Huang, Huoji Chen, Wanqing Wu, Huawen Huang, Huanfeng Jiang*. Copper-Catalyzed Oxidative [2+2+1] Cycloaddition: Regioselective Synthesis of 1,3-Oxazoles from Internal Alkynes and Nitriles. Chem. Sci. 2012, 3, 3463–3467. (IF: 9.969, Cited times: 105)
5. Bairong Liu, Jianhang Rao, Weibing Liu, Yang Gao, Yanping Huo, Qian Chen, Xianwei Li*, Ligand Assisted, Olefins Switched Divergent Oxidative Heck Cascade with Molecular Oxygen Enabled by Self-Assembled Imines. Org. Chem. Front., 2023, DOI: 10.1039/D3QO00316G. (Front Cover)
6. Zhongyuan Li, Xiaojian Chen, Hulin Zhong, Yitong Lin, Yang Gao, Yuan Liu, Qian Chen, Yanping Huo, Xianwei Li*, Expedient delivery of quinolinone drugs via a traceless N-nitroso enabled oxidative Heck/amidation cascade, Chem. Commun., 2022, 58, 13959–13962. (Invited contribution)
7. Wensen Ouyang, Bairong Liu, Yi He, Yanmei Wen, Yang Gao, Yanping Huo, Qian Chen, Xianwei Li*, Modular Construction of Functionalized Anilines via Switchable C–H and N-Alkylations of Traceless N-Nitroso Anilines with Olefins, Org. Chem. Front., 2022, 9, 2746–2752. (Invited contribution, Highlight by Frontiers Journal)
8. Aidong Huang, Yishen Han, Peiqing Wu, Yang Gao, Yanping Huo, Qian Chen, Xianwei Li*, Ligand Accelerated Site-Selective Csp2–H and Csp3–H Alkynylation of Alcohols via Pd(II) Catalysis, Org. Chem. Front., 2021, 8, 6484–6490. (Front Cover)
9. Wensen Ouyang, Xiaoqing Cai, Xiaojian Chen, Jie Wang, Jianhang Rao, Yang Gao, Yanping Huo, Qian Chen, Xianwei Li*, Sequential C–H Activation Enabled Expedient Delivery of Polyfunctional Arenes, Chem. Commun., 2021, 57, 8075–8078.
10. Wensen Ouyang, Jianhang Rao, Yibiao Li, Xiaohang Liu,c* Yanping Huo, Qian Chen, Xianwei Li,a* Recent Achievements in the Rhodium-Catalyzed Concise Construction of Medium N-Heterocycles, Azepines and Azocines, Adv. Synth. Catal. 2020, 362, 5576–5600.
11. Bifu Liu, Wensen Ouyang, Jianhong Nie, Yang Gao, Kejun Feng, Yanping Huo, Qian Chen, Xianwei Li*, Weak Coordinated Nitrogen Functionality Enabled Regioselective C–H Alkynylation via Pd(II)/Mono-N-Protected Amino Acid Catalysis, Chem. Commun., 2020, 56, 11255-11258. (Highlighted in CBG News)
12. Xianwei Li,* Wensen Ouyang, Jianhong Nie, Shaomin Ji, Qian Chen, Yanping Huo, Recent Development on Cp*Ir(III)-Catalyzed C—H Bond Functionalization, ChemCatChem, 2020, 12, 2358–2384. (Invited Review, Highlighted in Advanced Science News)
13. Xianwei Li, Guangxin Liang,* Zhang-Jie Shi,* Regio-Divergent C‒H Alkynylation with Janus Directing Strategy via Ir(III) Catalysis, Chin. J. Chem., 2020, 38, 929-934. (Front Cover, selected as ‘Break Report’, Highlighted by Chin. J. Chem.)
14. Guocai Wu, Wensen Ouyang, Qian Chen, Yanping Huo, Xianwei Li,* Cross-Dehydrogenative Alkynylation of Sulfonamides and Amides with Terminal Alkynes via Ir(III) Catalysis, Org. Chem. Front., 2019, 6, 284-289. (Front Cover, Hot Paper)