谢绍朐，博士，副教授，硕士生导师，广东工业大学“青年百人计划”A类引进人才。主要从事催化化学和化工分离工程的研究，以实现可再生能源、清洁燃料和化学品的生产。研究内容包括：1）生物质（纤维素，半纤维素，木质素，氨基酸，蛋白质，油脂，几丁质，发酵产物等）的催化转化，生产生物燃料和高附加值化学品；2）高效节能的生物基燃料和化学品的分离技术——盐析技术和糖析技术等液液萃取的开发； 3）CO2的捕集和转化，利用合成催化剂将胺捕集的二氧化碳直接转化为甲酸盐、甲醇、甲烷等化工原料，旨在实现可再生能源的零排放；4）设计新颖的工艺/催化剂来分解和升级废弃塑料；5）化学储氢。主持青年百人A启动基金；参与1项国家高技术研究发展计划（863计划），1项美国能源部项目，1项美国农业部项目，以及1项美国国家自然科学基金。在ACS Catalysis、Journal of Catalysis、AIChE Journal、ChemSusChem、ACS Sustainable Chemistry & Engineering， Iscience，Chem Catalysis等国际一流化工期刊上发表~40篇论文。获中国专利授权1项。

研究方向： 多相催化、均相催化、双相催化；生物燃料和生物化学品；CO₂的捕捉与转化；液液萃取；化工热力学与建模；系统工程（Aspen Plus）

教育经历

博士专业：化学工程

华南理工大学（2014.09-2017.06） 

导师: 邱学青 教授

研究方向: 分离;  盐析; 生物燃料; 催化过程

论文: 生物丁醇的盐析、糖析萃取技术与理论及其转化为燃料前驱体的研究

硕士专业：化学工程

华南理工大学 （2012.09-2014.09）

导师: 邱学青 教授

研究方向: 分离; 盐析; 生物燃料;催化过程

本科专业: 制药工程

华南理工大学 （2008.09-2012.06）

导师: 杨东杰 教授

研究项目: 漆酶修饰碱木质素的磺甲基化反应

工作经历

博士后 

美国华盛顿州立大学，化学工程与生物工程学院（2017.09-2021.06）

合作导师: Hongfei Lin 教授

https://labs.wsu.edu/hongfei_lin_group/people/

副教授 

广东工业大学，轻工化工学院（2021.06-至今）

科研项目

1. 广东工业大学“青年百人”科研启动基金，2021-2026，40万元，在研，主持

2. Commercialization Gap Fund (CGF), A Novel Sequential Catalytic Solvolysis Process for Deconstructing Waste Plastics, 2021-1至2021-12,4万美元，在研，参加

3. 美国能源部，DOE，ST217，A Reversible Liquid Hydrogen Carrier System Based on Ammonium Formate and Captured CO2，2020-2至2023-1,100万美元，在研，参加

4. 美国农业部，USDA，A1531, EFFICIENT PRODUCTION OF RENEWABLE JET FUEL AND BIO- AMINES FROM GENETICALLY OPTIMIZED CAMELINA, 2019-8至2023-8, 50万美元，在研，参加

5. The JOINT CENTER FOR AEROSPACE TECHNOLOGY INNOVATION, Development of pilot-scale biphasic catalytic process for production of sustainable aviation fuels, 2019-6至2020-6, 10万美元，已结题，参加

6. National Science Foundation, 1748579, Towards Sustainable Carbon-Negative Chemical Manufacturing by Creating Synergy between Carbon Dioxide Utilization and Biorefinery, 2017-9至2019-8, 11万美元，已结题，参加

7. 中国科技部，国家高技术研究发展计划(863计划)课题“生物制造分离过程技术与装备”子课题“盐析萃取技术及装备”， 2012-6至2015-6, 20万元，已结题，参加

联系方式

邮箱：xieshaoqu@foxmail.com; xieshaoqu@163.com; shaoqu.xie@gdut.edu.cn

地址：广州市大学城外环西路100号广东工业大学工学四号馆

研究生招生

学术型硕士：化学工程与技术

专业型硕士：化学工程

研究概况

(1)多相催化和均相催化制备生物基燃料和化学品

将化学过程与新型材料相结合，用于生物质基化学品和清洁燃料的生产。原料包括纤维素、木质素、甲壳素、蛋白质、植物油、发酵液等。通过分离过程和化学反应的耦合也是研究方向之一，例如通过双相催化过程直接将生物质转化为生物燃料、含氮化学品，特别是生物质转化成含氮化学品。

(2)生物基燃料和化学品新型分离过程的开发

乙醇、丙酮、正丁醇、异丁醇、1,3-丙二醇、2,3-丁二醇等是优良的有机溶剂和有机合成的原料。工业上生产这些化学品包含了合成法与发酵法。化学合成法的原料来源于化石资源，而发酵法的原料为可再生的生物质资源。随着化石资源的日益减少，发酵法生产这些产物得到人们的高度重视。传统的精馏工段要除去发酵固形物和大部分水分，从而导致发酵法的能耗大，如分离纯化ABE的工业应用中，每生产1吨ABE，约需18吨蒸汽。因此我们开发了高效节能的生物基燃料和化学品的分离技术——盐析技术和糖析技术。

我们采用盐析技术除去发酵液或者发酵液浓缩液的水分，降低后续分离中共沸物或者水的含量，采用“盐析+精馏”工艺分离生物基燃料和化学品，达到高效节能的目的。图6显示了“蒸馏-盐析-精馏”的方法分离ABE的过程，该工艺流程比传统的单纯精馏过程节能35%以上。我们也采用了糖析技术除去发酵液浓缩液的水分，降低正丁醇+水共沸物的量，萃余液主要为糖溶液，可用于下一步的ABE发酵，减少了萃余液回收过程，节能效果明显。

(3)CO₂的捕获和转化

通过工业技术实现碳循环确实可以解决两个主要问题，即“全球变暖”和“能源危机”。我们的研究重点是利用多相催化剂将胺捕集的二氧化碳直接转化为甲酸盐、甲醇、甲烷等化工原料。CO₂捕集和利用(CCU)往往是单独进行的，导致CO₂和转化产物分离过程的高能耗。捕集剂通过化学方式结合CO₂分子，将顽固的CO₂激活成更活跃的物种。将活性物种直接转化为有附加值的化学品，简化了CO₂的利用过程，省去了CO₂分离过程，节能效果强。我的研究重点是利用多相催化剂将胺捕获的二氧化碳直接转化为甲酸盐，甲醇，甲烷等化工原料。

(4)设计新颖的工艺/催化剂来分解和升级废塑料

研究的目的是探索一种可工业化的催化技术，从废塑料中生产有价值的聚合物单体和燃料。该技术可简化催化过程和分离过程，得到高收率和高纯度的聚合物单体和燃料。推荐的工艺是使用工业或自合成催化剂，将包括聚酯，聚烯烃，聚氨酯，聚酰胺等在内的塑料进行转化，以生产聚合物单体和汽油、航空煤油、柴油等燃料.

论文和专利

Google Scholar

https://scholar.google.com/citations?user=_neKThcAAAAJ&hl=zh-CN

Researchgate

https://www.researchgate.net/profile/Shaoqu-Xie

(1)Chuhan Fu, Zhuoxi Li, Yulei Zhang, Conghua Yi, Shaoqu Xie*. Assessment of extraction options for a next‐generation biofuel: Recovery of bio‐isobutanol from aqueous solutions. Engineering in Life Sciences. 2021,21(10), 653-665(期刊论文)

(2)Shaoqu Xie, Zengran Sun, Tuan, Liu, Jinwen Zhang, Tianjin Li, Xinping Ouyang, Xueqing Qiu, Song Luo, Wei Fan, Hongfei Lin. Beyond biodegradation: Chemical upcycling of poly (lactic acid) plastic waste to methyl lactate catalyzed by quaternary ammonium fluoride. Journal of Catalysis, 2021, 402: 61-71. (期刊论文)

 (3) Xie, Shaoqu; Zhang, Wanli; Jia, Chuhua; Ong, Scott Sergio Go; Zhang, Cheng; Zhang, Shicheng; Lin, Hongfei*; Eliminating carbon dioxide emissions at the source by the integration of carbon dioxide capture and utilization over noble metals in the liquid phase , Journal of Catalysis, 2020, 389: 247-258.(期刊论文)

(4) Xie, Shaoqu; Jia, Chuhua; Wang, Ziling; Ong, Scott Sergio Go; Zhu, Mei-jun; Lin, Hongfei*; Mechanistic Insight into Selective Deoxygenation of L-Lysine to Produce Biobased Amines , ACS Sustainable Chemistry & Engineering, 2020, 8(31): 11805-11817. (期刊论文)

(5) Xie, Shaoqu; Jia, Chuhua; Ong, Scott Sergio Go; Wang, Ziling; Zhu, Mei-Jun; Wang, Qiaojuan; Yang, Yanhui; Lin, Hongfei*; A Shortcut Route to Close Nitrogen Cycle: Bio-Based Amines Production via Selective Deoxygenation of Chitin Monomers over Ru/C in Acidic Solutions. , iScience, 2020, 23(5): 101096. (期刊论文)

(6) Xie, Shaoqu#; Jia, Chuhua#; Prakash, Arushi; Palafox, Mackenzie Irene; Pfaendtner, Jim; Lin, Hongfei*; Generic Biphasic Catalytic Approach for Producing Renewable Diesel from Fatty Acids and Vegetable Oils , ACS Catalysis, 2019, 9(4): 3753-3763. (期刊论文)

(7) Xie, Shaoqu; Yi, Conghua*; Qiu, Xueqing*; Salting-out of acetone, 1-butanol, and ethanol from dilute aqueous solutions , AIChE Journal, 2015, 61(10): 3470-3478. (期刊论文)

 (8) Jia, C., Xie, S., Zhang, W., Intan, N. N., Sampath, J., Pfaendtner, J., & Lin, H. (2021). Deconstruction of high-density polyethylene into liquid hydrocarbon fuels and lubricants by hydrogenolysis over Ru catalyst. Chem Catalysis.

(9) C Jia, C Zhang, S Xie, W Zhang, Z Wang, H Lin. One-Pot Production of Jet Fuels from Fatty Acids and Vegetable Oils in Biphasic Tandem Catalytic Process. Fuel

(10)Wanli Zhang; Yao Yao; Shaoqu Xie; Kristian Gubsch; Yanhui Yang; Xingying Lan; Hongfei Lin; Synergistic interaction between Cu and ZrO2 promotes ethyl formate hydrogenation to produce methanol , Catalysis Today, 2021, 374,15,53-60

(11) Chuhan Fu; Zhuoxi Li; Chuhua Jia; Wanli Zhang; Yulei Zhang; Conghua Yi; Shaoqu Xie*; Recent advances on bio-based isobutanol separation, Energy Conversion and Management: X, 2020, 10: 0-100059. (期刊论文)

(12) Xie, Shaoqu#; Zhang, Wanli#; Lan, Xingying*; Lin, Hongfei*; CO2 Reduction to Methanol in the Liquid Phase: A Review. , Chemsuschem, 2020, 13(23): 6141-6159. (期刊论文)

(13) Fu, Chuhan; Li, Zhuoxi; Song, Wenli; Yi, Conghua*; Xie, Shaoqu*; A new process for separating biofuel based on the salt+1-butanol+water system, Fuel, 2020, 278: 0-118402. (期刊论文)

(14) Xie, Shaoqu; Huynh, Trong H.; Qin, Peiyong; Tan, Tianwei; Lin, Hongfei*; Facile biphasic catalytic process for conversion of monoterpenoids to tricyclic hydrocarbon biofuels , Journal of Energy Chemistry, 2020, 49: 42-50.(期刊论文)

(15) Fu, Chuhan; Li, Zhuoxi*; Sun, Zengran; Xie, Shaoqu*; A review of salting-out effect and sugaring-out effect: driving forces for novel liquid-liquid extraction of biofuels and biochemicals , Frontiers of Chemical Science and Engineering. (期刊论文)

(16) Chuhan Fu; Shaoqu Xie*; Salts and 1‐propanol induced aqueous two‐phase systems: phase separation and application, Journal of Chemical Technology & Biotechnology, 2019, 94(7): 2372-2381. (期刊论文)

(17) Chuhan Fu; Wenli Song; Conghua Yi; Shaoqu Xie*; Creating efficient novel aqueous two-phase systems: Salting-out effect and high solubility of salt, Fluid Phase Equilibria, 2019, 490: 77-85. (期刊论文)

(18) Xie, Shaoqu*; Fu, Chuhan; Song, Wenli; Zhang, Yulei; Yi, Conghua*; Highly efficient synthesis and separation of fuel precursors from the concentrated ABE fermentation broth in a biphasic catalytic process , Fuel, 2019, 242: 41-49. (期刊论文)

(19) Zhang, Cheng; Jia, Chuhua; Cao, Yang; Yao, Yao; Xie, Shaoqu; Zhang, Shicheng*; Lin, Hongfei*; Water-assisted selective hydrodeoxygenation of phenol to benzene over the Ru composite catalyst in the biphasic process , Green Chemistry, 2019, 21(7): 1668-1679. (期刊论文)

(20) Tang, Kan; Xie, Shaoqu; Cofield, Gabriel Ross; Yang, Xiaokun; Tian, Emmy; Lin, Hongfei*; Catalytic Transfer Hydrogenation of Furfural for the Production of Ethyl Levulinate: Interplay of Lewis and Bronsted Acidities , Energy Technology, 2018, 6(9): 1826-1831. (期刊论文)

(21) Shaoqu Xie; Xiao Zhang; Michael P Walcott; Hongfei Lin; Applications of Cellulose Nanocrystals：A Review , Engineered Science, 2018, 2: 4-16.(期刊论文)

(22) Xie, Shaoqu; Song, Wenli; Fu, Chuhan; Yi, Conghua*; Qiu, Xueqing*; Separation of acetone: From a water miscible system to an efficient aqueous two-phase system , Separation and Purification Technology, 2018, 192: 55-61.(期刊论文)

(23) Yi, Conghua; Zhang, Yulei; Xie, Shaoqu; Song, Wenli; Qiu, Xueqing*; Salting-out extraction of bio-based isobutanol from an aqueous solution , Journal of Chemical Technology and Biotechnology, 2018, 93(2): 372-384. (期刊论文)

(24) Xie, Shaoqu; Song, Wenli; Yi, Conghua*; Qiu, Xueqing*; Salting-out extraction systems of ethanol and water induced by high-solubility inorganic electrolytes , Journal of Industrial and Engineering Chemistry, 2017, 56: 145-150. (期刊论文)

(25) Xie, Shaoqu; Zhang, Yulei; Yi, Conghua*; Qiu, Xueqing*; Biobutanol recovery from model solutions using potassium pyrophosphate , Journal of Chemical Technology and Biotechnology, 2017, 92(6): 1229-1235. (期刊论文)

(26) Xie, Shaoqu; Zhang, Yulei; Zhou, Yong; Wang, Zeru; Yi, Conghua*; Qiu, Xueqing*; Salting-out of bio-based 2,3-butanediol from aqueous solutions , Journal of Chemical Technology and Biotechnology, 2017, 92(1): 122-132. (期刊论文)

(27) Xie, Shaoqu; Yi, Conghua*; Qiu, Xueqing*; Salting-out effect of potassium pyrophosphate (K4P2O7) on the separation of biobutanol from an aqueous solution, Journal of Chemical Technology and Biotechnology, 2016, 91(6): 1860-1867. (期刊论文)

(28) Xie, Shaoqu; Qiu, Xueqing*; Ji, Weini; Yi, Conghua*; Salting-out of 1,3-propanediol from aqueous solutions by inorganic electrolytes , Journal of Chemical Technology and Biotechnology, 2016, 91(11): 2793-2801. (期刊论文)

(29) Zhou, Haifeng; Qiu, Xueqing*; Yang, Dongjie; Xie, Shaoqu; Laccase and Xylanase Incubation Enhanced the Sulfomethylation Reactivity of Alkali Lignin, ACS Sustainable Chemistry & Engineering, 2016, 4(3): 1248-1254. (期刊论文)

(30) Xie, Shaoqu; Ji, Weini; Zhang, Yulei; Zhou, Yong; Wang, Zeru; Yi, Conghua*; Qiu, Xueqing*; Biobutanol recovery from model solutions/fermentation broth using tripotassium phosphate , Biochemical Engineering Journal, 2016, 115: 85-92. (期刊论文)

(31) Xie, Shaoqu; Qiu, Xueqing; Yi, Conghua*; Separation of a Biofuel: Recovery of Biobutanol by Salting-Out and Distillation , Chemical Engineering & Technology, 2015, 38(12): 2181-2188. (期刊论文)

(32) Xie, Shaoqu; Zhang, Suwen; Qiu, Xueqing*; Yi, Conghua; Hu, Yun; Li, Fuhang; Quan, Jinhua; Sugaring-Out Effects of Sucrose and Glucose on the Liquid-Liquid Equilibria for the (Water plus Acetone+1-Butanol + Ethanol) System , Journal of Chemical and Engineering Data, 2015, 60(8): 2434-2441.(期刊论文)

(33) Xie, Shaoqu; Qiu, Xueqing; Yi, Conghua*; Salting-out effect of tripotassium phosphate on the liquid–liquid equilibria of the (water+acetone+1-butanol+ethanol) system and the salting-out recovery , Fluid Phase Equilibria, 2015, 386: 7-12. (期刊论文)

(34) Yi, Conghua; Xie, Shaoqu; Qiu, Xueqing*; Salting-Out Effect of Dipotassium Hydrogen Phosphate on the Recovery of Acetone, Butanol, and Ethanol from a Prefractionator , Journal of Chemical and Engineering Data, 2014, 59(5): 1507-1514. (期刊论文)

(35) Xie, Shaoqu; Yi, Conghua; Qiu, Xueqing*; Energy-Saving Recovery of Acetone, Butanol, and Ethanol from a Prefractionator by the Salting-Out Method, Journal of Chemical and Engineering Data, 2013, 58(11): 3297-3303. (期刊论文)

(36) Yang, Dong-jie*; Zhou, Hai-feng; Xie, Shao-qu; Wu, Xiao-lei; Qiu, Xue-qing; SULFOMETHYLATION REACTIVITY OF ALKALI LIGNIN WITH LACCASE MODIFICATION, Acta Polymerica Sinica, 2013, (2): 232-240. (期刊论文)

(37) Shaoqu Xie,* Zhuixi Li, Guodian Zhu, Conghua Yi, One-pot reaction-separation process to produce jet fuel. Energy Conversion and Management: X (2021).

中国专利

邱学青 谢绍朐 易聪华 楼宏铭 杨东杰。乙醇、丙酮和正丁醇的盐析复合精馏分离回收的方法及装置，授权公告CN 104086391 B，授权公告日2016.01.06

美国专利

Hongfei Lin, Shaoqu Xie, Conversion of co-mingled waste plastics to monomers and fuels in sequential catalytic process. In application. Application number: 62902712